Uspekhi Khimii Gem.-Digalogentsiklopropanov
Bogomazova Anna,Mikhaylova Natal'ya,Zlotskiy Semen
Uspekhi Khimii Gem.-Digalogentsiklopropanov
Bogomazova Anna,Mikhaylova Natal'ya,Zlotskiy Semen
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gem.-Digalogentsiklopropany legko obrazuyutsya v rezul'tate [2]1]-prisoedineniya digalogenkarbenov po kratnym uglerod-uglerodnym svyazyam. Eti soedineniya predstavlyayut znachitel'nyy interes kak poluprodukty i reagenty v sinteze biologicheski aktivnykh preparatov. Kniga posvyashchena sovremennym problemam polucheniya i transformatsii gem.-digalogentsiklopropanov razlichnogo stroeniya. V ney rassmotreny osnovnye puti obrazovaniya gem.-digalogentsiklopropanovykh struktur; rassmotreno vliyanie stroeniya nepredel'nykh soedineniy i karbenov na regio- i stereoselektivnost’ [2]1]-prisoedineniya. Pokazano, chto digalogenkarbeny sposobny vnedryat'sya po slabym uglerod-vodorodnym svyazyam, smezhnym s geteroatomami. Rassmotreny reaktsii gem.-digalogentsiklopropanov (O-, N-, C-alkilirovanie, gomo- i sopolimerizatsiya, vosstanovlenie i okislenie), protekayushchie s zameshcheniem galogenov, libo s rasshchepleniem karbotsikla. Pri etom, okazyvaetsya vozmozhnym kak poluchenie polizameshchennykh tsiklicheskikh soedineniy, tak i obrazovanie atsiklicheskikh alkenov i alkinov, soderzhashchie geteroatomy. Kniga prednaznachena dlya studentov, aspirantov, prepodavateley, a takzhe dlya shirokogo kruga khimikov-organikov, rabotayushchikh v oblasti organicheskogo kataliza.
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