Teploakkumuliruyushchie Materialy Na Osnove Sistemy Li, CA//F, CL, So4, Moo4
Dibirov Yakhya
Teploakkumuliruyushchie Materialy Na Osnove Sistemy Li, CA//F, CL, So4, Moo4
Dibirov Yakhya
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Kniga posvyashchena razrabotke energoemkikh fazoperekhodnykh, termokhimicheskikh i fazoperekhodno-termokhimicheskikh materialov dlya akkumulirovaniya teplovoy energii na osnove izucheniya fazovykh ravnovesiy sistemy iz vos'mi soley, v sostav kotoroy vkhodyat kal'tsievye prirodnye mineraly: plavikovyy shpat (CaF2), angidrit (CaSO4), povellit(CaMoO4) i litievye soli, obladayushchie vysokimi znacheniyami ental'piy fazovykh perekhodov. Predlozhen razrabotannyy avtorom metod rascheta standartnykh znacheniy termodinamicheskikh svoystv dvoynykh soedineniy podborom sostavov figurativnykh tochek raznymi sochetaniyami ingredientov stabil'nogo i metastabil'nogo kompleksov vzaimnykh sistem. Vyyavleny uravneniya khimicheskikh reaktsiy, sootvetstvuyushchie troynym, chetvernym i pyaternoy vzaimnym sistemam i rasschitany ikh teplovye effekty v intervale temperatur 600 - 1000 K. Opredeleny teplofizicheskie i termodinamicheskie parametry 50 nonvariantnykh sostavov issleduemoy sistemy. Razrabotannye sostavy, kristallizuyushchiesya v intervale temperatur 675 - 1247 K i reaktsii vzaimnogo obmena rekomenduyutsya ispol'zovat’ kak teplonakopiteli pri proektirovanii fazoperekhodnykh, termokhimicheskikh, fazoperekhodno-termokhimicheskikh teplovykh akkumulyatorov.
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