Sovremennaya Khimiya Tsiklicheskikh Atsetaley
Bogomazova Anna,Mikhaylova Natal'ya,Zlotskiy Semen
Sovremennaya Khimiya Tsiklicheskikh Atsetaley
Bogomazova Anna,Mikhaylova Natal'ya,Zlotskiy Semen
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Tsiklicheskie atsetali predstavlyayut soboy vazhneyshiy klass nasyshchennykh geterotsiklicheskikh soedineniy s dvumya atomami kisloroda. Tsikloatsetal'nyy fragment legko obrazuetsya pri kondensatsii karbonil'nykh soedineniy s glikolyami i chasto prisutstvuet v molekulakh razlichnykh biologicheski aktivnykh i lekarstvennykh preparatov. Naryadu s etim tsiklicheskie atsetali nakhodyat shirokoe primenenie v razlichnykh oblastyakh nauki i tekhniki. V chastnosti 4,4-dimetil-1,3-dioksan yavlyaetsya poluproduktom v krupnotonnazhnom promyshlennom sinteze izoprena. V dannoy knige rassmatrivayutsya i obsuzhdayutsya rezul'taty izucheniya khimii tsiklicheskikh atsetaley za poslednie desyatiletiya. Rassmotreny sovremennye puti sinteza i ryad novykh perspektivnykh napravleniy transformatsii i funktsionalizatsii tsiklicheskikh atsetaley razlichnogo stroeniya. Pokazana vozmozhnost’ radikal'noy zhidkofaznoy peregruppirovki tsiklicheskikh atsetaley v izomernye slozhnye efiry. V rabote sistematizirovany svedeniya o geterotsiklicheskikh reaktsiyakh tsiklicheskikh atsetaley, kotorye protekayut v prisutstvii razlichnykh kislotnykh katalizatorov. Kniga prednaznachena dlya studentov, aspirantov i prepodavateley, a takzhe dlya shirokogo kruga khimikov-organikov, rabotayushchikh v oblasti organicheskogo sinteza
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