Organic Chemistry Using Clays

The development of appropriate catalytic systems in the syn- thesis of fine chemicals is in constant progress. This book provides an overview of organicreactions catalyzed by clays (natural, activated and modified, including

pillard clays) or performed by clay-supported reagents. The book should

be of considerable interest to all research groups (academic and

industrial) involved in heterogeneous catalysis. Organic reactions on clays are organized by reaction type. A rather comprehensive coverage of the

literature is perfor- med, including patent literature. Throughout, the

approach to the subject is rational rather than empirical. From the

contents: Acylation of Aromatic Compounds - Alkyla- tion, Dealkylations,

Transalkylations, Disproportionations - Halogenations - Nitrations -

Miscellaneous Substitution Re- actions - Addition Reaction - Elimination

Reactions - Oxida- tion, Dehydrogenation Reactions - Aromatization -

Hydrogena- tion, Hydrogenloysis - Cyclization Reactions -

Diels-Alder Reactions - Isomerization - Dimerization, Oxidative

Dimeri- zation - Rearrangements - Condensation Reactions - Thermal and Hydrolytic Decompositions - Reactions of Carbonyl Com- pounds - Reactions ofCarboxylic Acids and Derivatives - Amino Acid and Peptide Formation Under
Prebiotic Conditions - Miscellaneous Reactions.