Nitroksil'nye Radikaly V Khimicheskikh I Biokhimicheskikh Protsessakh
Pliss Evgeniy,Sen' Vasiliy,Tikhonov Ivan
Nitroksil'nye Radikaly V Khimicheskikh I Biokhimicheskikh Protsessakh
Pliss Evgeniy,Sen' Vasiliy,Tikhonov Ivan
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Reaktsii stabil'nykh nitroksil'nykh radikalov i produktov ikh prevrashcheniya (gidroksilaminov i alkoksiaminov) uzhe svyshe pyatidesyati let vyzyvayut neoslabevayushchiy interes issledovateley, rabotayushchikh v takikh razlichnykh oblastyakh kak fizicheskaya organicheskaya khimiya, khimiya i fizika vysokomolekulyarnykh soedineniy, biofizika, molekulyarnaya biologiya i meditsina. Predpolagaetsya, chto nitroksily vliyayut na zhiznesposobnost’ kletki cherez redoks-oposredovannye signaly i indutsiruyut gibel’ kletok, zavisyashchuyu ot mnogikh faktorov, vklyuchaya okislitel'noe povrezhdenie, ostanovku kletochnogo tsikla i apoptoz. Issledovanie molekulyarnykh mekhanizmov etikh protsessov yavlyaetsya odnoy iz prioritetnykh zadach sovremennoy onkologii. Osobenno intensivno i uspeshno issledovaniya antioksidantnoy aktivnosti nitroksil'nykh radikalov i ikh proizvodnykh v khimicheskikh i biokhimicheskikh protsessakh razvivayutsya v poslednee desyatiletie. Analiz etikh rezul'tatov i ikh sravnenie s izvestnymi ranee kontseptsiyami i teoriyami i stal predmetom nastoyashchey monografii. Kniga prednaznachena dlya spetsialistov, rabotayushchikh v sfere kinetiki radikal'no-tsepnykh reaktsiy, i dlya issledovateley, zanimayushchikhsya problemami biokhimii i meditsiny.
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